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4-22 Lucifer Rising When the last few of the 66 Seals are broken by Lilith's minions, Sam and Dean prepare for the big and probably futile fight in very different ways. Sam joins Ruby on a final attempt to kill Lilith before Lucifer rises, while Castiel and Zachariah tell Dean that it's time to play his part in stopping Lucifer.
5-01 Sympathy for the Devil In the aftermath of the Devil rising, Sam and Dean are whisked away and they are given a message from Chuck Shurley that Castiel is dead and that Luficer walks the Earth. As a result, Sam and Dean turn to Bobby for help to find a mystical weapon, called Michael's Sword. This will enable them to find the Devil before he takes on a new form to bring the slow end of the world. But the Winchester brothers are pitted against the archangel Zachariah who has plans for Dean, as well as more demons. Sam and Dean recognise a demon, Meg, who has returned from Hell.
3-11 Mystery Spot Sam relives the same day over and over, continually having to deal with Dean's death.
2-01 In My Time Of Dying In the aftermath of the car crash, the surviving Winchesters go to the hospital, where one is stalked by a Reaper while another must consider sacrificing himself to save the others.
3-12 Jus in Bello Sam and Dean are arrested by Agent Henriksen and thrown into a jail cell in Colorado just as an army of demons makes their first move under a new leader who wants Sam dead.
3-13 Ghost Facers Sam and Dean inexplicably encounter the Hell Hounds while investigating a case that John failed to crack years earlier and become fixtures in their pilot for a reality show called Ghostfacers.
2-03 Bloodlust The Winchester brothers enjoy Dean's new baby: a shiny newly restored car, while checking out a report of two recent human deaths and over a dozen split-open cows in the small town of Red Lodge, Montana. The local sheriff laughs at Sam and Dean's idea that a cult is behind it, claiming it happens naturally in the sun. But when Sam and Dean sneak into the morgue under false pretenses, they find a victim that has retractable vampire fangs. They catch black demon hunter Gordon Walker, who claims to be a friend of their late father and having made both kills after six months of vampire chasing started years before to avenge his sister who was killed by a vampire. Dean confesses to him he misses his seemingly unstoppable dad desperately. The boys are just in time to save Gordon from another vampire, but Ellen Harvelle warns Sam that Gordon is capable, but too dangerous to work with. Returning to the motel, Sam is knocked down and kidnapped by the vampires led by Eli and Lenore, who claim their kind feeds on only cows. Being released unharmed, Sam believes them, but feels Dean's fist for forsaking their mission and suggesting Dean joins Gordon as a poor substitute for father. Then Gordon goes after the nest alone, anyway...
3-04 Sin City The Winchester boys head to Ohio to research several deaths in a small town, where sin has taken a firm foothold on the population; prostitution, adultery, alcohol abuse, murder, and suicide are all prevalent in the once quiet town. Dean has a revealing conversation with a demon possessed woman. The demon Ruby assists Bobby in restoring the Colt to it's demon-killing grandeur.
4-03 In The Beginning Castiel sends Dean back in time to 1973 where he encounters younger versions of his parents and for the first time meets his grandfather Samuel Campbell who holds a secret that sheds a light on the Winchester Family's connection to the hunter community.
2-12 Nightshifter A jewelery store heist committed by an employee is linked to a mysterious bank robberies bring Sam and Dean into the chase. The weird part seems to be the fact that the suspects end up dead before even getting their hands on the money. A friendly tip points towards another shapeshifter. However, the search is interrupted by a hostage crisis.
5-09 The Real Ghostbusters Dean and Sam are on a Supernatural convention where they meet lots of fans of the Supernatural Comic Books. After a while they get the impression that something is not right at the location of the convention.
5-08 Changing Channels Sam and Dean catch up with the Trickster, who sends them through a dizzying montage of TV show parodies, inviting them to play along with their "roles" or be stuck in "TV Land" forever. But once Castiel shows up, the boys get an idea as to what the Trickster might be hiding and eventually come up with a surprising answer.
5-13 The Song Remains the SameThe angels send Anna back in time to kill John and Mary Winchester before they can conceive Sam knowing that if Sam was never born then Lucifer won't be able to use him as his vessel. Castiel sends Sam and Dean back to 1978 so they can stop Anna, and the two brothers are reunited with their parents. Mary recognizes Dean as a hunter since he visited her in the past once before but tries to keep the truth from John.
5-14 My Bloody Valentine Castiel helps Sam and Dean hunt down Cupid (guest star Lex Medlin) on Valentine's Day after townspeople start to kill each other for love. However, after Cupid tells them he's innocent, they discover Famine (guest star James Otis), one of the Four Horsemen of the Apocalypse, has arrived in town.
5-15 Dead Men Don't Wear Plaid Sam and Dean investigate Bobby's home town where the dead are rising from the grave but instead of attacking humans, they are happily reuniting with their families. The brothers turn to Bobby for help but he tells them not to worry about it and to leave town. Suspicious, Dean investigates and comes face to face with Bobby's dead wife who has no memory of what happened to her. Once the zombies start turning evil, the boys tell Bobby he has to kill his wife but he refuses.
5-17 99 Problems As Sam and Dean arrive in a small town they discover it is under demon attack. Strangely the daughter of the local pastor is having visions and is giving guidance to the townsfolk as a prophet. Guiding them and advising them she has built up their trust and blind faith. But things are not what they seem as Sam and Dean discover the truth when Castiel shows up.
5-19 Hammer of the Gods Sam and Dean are kidnapped by a group of gods, including Kali, Ganesh and Baldur and held hostage in a small hotel. The gods want to use Sam and Dean as bargaining chips to stop the Apocalypse, but Gabriel shows up and warns them that if Lucifer finds them he will kill them all. Unfortunately, one of the gods turns on the rest and Lucifer appears
5-20 The Devil You Know The demon Crowley tells Sam and Dean he can help them find the remaining Horsemen rings so they can trap Lucifer. The brothers are doubtful until Crowley leads them to Brady, the Handler for Pestilence and Death. However, Brady refuses to give up their locations and sets Pestilence after the Winchesters.
5-21 Two Minutes to Midnight Crowley tells Bobby he will give him the location of Death, the fourth horseman, in exchange for his soul. Sam and Dean confront Pestilence, but he unleashes a deadly virus upon them, so Castiel must intervene on their behalf. Dean has a meeting with Death to discuss Lucifer, and an unholy alliance is formed at a very high price for Dean.
5-22 Swan Song With the Apocalypse looming, Sam and Dean realize they are out of options and make heart-breaking decisions that will change their lives forever. A beloved character is killed.
...in this order